 USA: US Open - Doubles - Main |
|---|
| 1/32-finals | Hradecka L./Noskova L. | Williams S./Williams V. | 2:0 (7:65, 6:4) | details | 02.09.2022 |
| USA: Indian Wells - Doubles - Main |
|---|
| 1/16-finals | Williams S./Williams V. | Brady J./Riske-Amritraj A. | CAN. | details | 07.03.2019 |
 France: French Open - Doubles - Main |
|---|
| 1/8-finals | Williams V./Williams S. | Klepac A./Martinez Sanchez M. J. | 1:2 (4:6, 7:64, 0:6) | details | 03.06.2018 |
| 1/16-finals | Williams V./Williams S. | Errani S./Flipkens K. | 2:0 (6:4, 6:2) | details | 01.06.2018 |
| 1/32-finals | Aoyama S./Kato M. | Williams V./Williams S. | 1:2 (6:4, 4:6, 1:6) | details | 30.05.2018 |
 World: Fed Cup - World Group - Doubles - Main |
|---|
| | Williams S./Williams V. | Pattinama Kerkhove L./Schuurs D. | 0:2 (2:6, 3:6) | details | 11.02.2018 |
 Australia: Australian Open - Doubles - Main |
|---|
| 1/32-finals | Williams S./Williams V. | Babos T./Pavlyuchenkova A. | CAN. | details | 18.01.2017 |
| World: Olympic Games - Doubles - Main |
|---|
| 1/16-finals | Williams S./Williams V. | Safarova L./Strycova B. | 0:2 (3:6, 4:6) | details | 07.08.2016 |
 United Kingdom: Wimbledon - Doubles - Main |
|---|
| Final | Babos T./Shvedova Y. | Williams S./Williams V. | 0:2 (3:6, 4:6) | details | 09.07.2016 |
| Semi-finals | Williams S./Williams V. | Goerges J./Pliskova Ka. | 2:0 (7:63, 6:4) | details | 08.07.2016 |
| Quarter-finals | Williams S./Williams V. | Makarova E./Vesnina E. | 2:1 (7:61, 4:6, 6:2) | details | 07.07.2016 |
| 1/8-finals | Sestini Hlavackova A./Hradecka L. | Williams S./Williams V. | 0:2 (4:6, 3:6) | details | 05.07.2016 |
| 1/16-finals | Mertens E./Mestach A.S. | Williams S./Williams V. | 0:2 (4:6, 4:6) | details | 02.07.2016 |
| France: French Open - Doubles - Main |
|---|
| 1/8-finals | Williams S./Williams V. | Bertens K./Larsson J. | 0:2 (3:6, 3:6) | details | 29.05.2016 |
| 1/16-finals | Diatchenko V./Voskoboeva G. | Williams S./Williams V. | 1:2 (68:7, 6:4, 0:6) | details | 29.05.2016 |
 Italy: Rome - Doubles - Main |
|---|
| 1/16-finals | Williams S./Williams V. | Klepac A./Srebotnik K. | 0:2 (1:6, 5:7) | details | 09.05.2016 |
| Australia: Australian Open - Doubles - Main |
|---|
| 1/32-finals | Medina Garrigues A./Shvedova Y. | Williams S./Williams V. | CAN. | details | 21.01.2015 |
| USA: US Open - Doubles - Main |
|---|
| Quarter-finals | Williams V./Williams S. | Makarova E./Vesnina E. | 0:2 (65:7, 4:6) | details | 02.09.2014 |
| 1/8-finals | Williams V./Williams S. | Muguruza G./Suarez Navarro C. | 2:0 (6:1, 6:0) | details | 31.08.2014 |
| 1/16-finals | Williams V./Williams S. | Kalashnikova O./Savchuk O. | 2:0 (6:2, 6:1) | details | 30.08.2014 |
| 1/32-finals | Babos T./Mladenovic K. | Williams V./Williams S. | 1:2 (60:7, 7:64, 1:6) | details | 28.08.2014 |
 United Arab Emirates: Dubai - Doubles - Main |
|---|
| 1/8-finals | Williams S./Williams V. | Makarova E./Vesnina E. | 1:2 (4:6, 6:4, 4:10) | details | 19.02.2014 |
| Australia: Australian Open - Doubles - Main |
|---|
| 1/32-finals | Williams V./Williams S. | Mladenovic K./Pennetta F. | 0:0 CAN. | details | 17.01.2014 |
 China: Beijing - Doubles - Main |
|---|
| 1/16-finals | Williams S./Williams V. | Chan H-C./Huber L. | 1:2 (7:63, 4:6, 9:11) | details | 30.09.2013 |
| Australia: Australian Open - Doubles - Main |
|---|
| Quarter-finals | Errani S./Vinci R. | Williams S./Williams V. | 2:1 (3:6, 7:61, 7:5) | details | 22.01.2013 |
| 1/8-finals | Williams S./Williams V. | Petrova N./Srebotnik K. | 2:0 (6:2, 6:3) | details | 20.01.2013 |
| World: Olympic Games - Doubles - Main |
|---|
| Final | Sestini Hlavackova A./Hradecka L. | Williams S./Williams V. | 0:2 (4:6, 4:6) | details | 05.08.2012 |
| Semi-finals | Kirilenko M./Petrova N. | Williams S./Williams V. | 0:2 (5:7, 4:6) | details | 04.08.2012 |
| Quarter-finals | Williams S./Williams V. | Errani S./Vinci R. | 2:0 (6:1, 6:1) | details | 02.08.2012 |
| 1/8-finals | Kerber A./Lisicki S. | Williams S./Williams V. | 0:2 (2:6, 5:7) | details | 31.07.2012 |
