 United Arab Emirates: Abu Dhabi - Singles - Main |
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| 1/16-finals | Pliskova Ka. | Muguruza G. | CAN. | details | 07.02.2023 |
 France: Lyon - Singles - Main |
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| 1/16-finals | Noskova L. | Muguruza G. | 2:0 (6:1, 6:4) | details | 30.01.2023 |
 Australia: Australian Open - Singles - Main |
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| 1/64-finals | Muguruza G. | Mertens E. | 1:2 (6:3, 63:7, 1:6) | details | 17.01.2023 |
| Australia: Adelaide - Singles - Main |
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| 1/16-finals | Muguruza G. | Bencic B. | 0:2 (3:6, 4:6) | details | 09.01.2023 |
| Australia: Adelaide 2 - Singles - Main |
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| 1/16-finals | Muguruza G. | Andreescu B. | 1:2 (6:0, 63:7, 1:6) | details | 01.01.2023 |
 USA: San Diego - Singles - Main |
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| 1/16-finals | Zheng Q. | Muguruza G. | 0:0 RET. (5:0) | details | 12.10.2022 |
| 1/16-finals | Rybakina E. | Muguruza G. | CAN. | details | 12.10.2022 |
 Japan: Tokyo - Singles - Main |
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| Quarter-finals | Samsonova L. | Muguruza G. | 2:0 (6:4, 6:2) | details | 23.09.2022 |
| 1/8-finals | Papamichail D. | Muguruza G. | 0:2 (4:6, 2:6) | details | 21.09.2022 |
| USA: US Open - Singles - Main |
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| 1/16-finals | Muguruza G. | Kvitova P. | 1:2 (7:5, 3:6, 610:7) | details | 03.09.2022 |
| 1/32-finals | Muguruza G. | Fruhvirtova L. | 2:0 (6:0, 6:4) | details | 01.09.2022 |
| 1/64-finals | Muguruza G. | Tauson C. | 2:0 (6:3, 7:65) | details | 30.08.2022 |
| USA: Cincinnati - Singles - Main |
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| 1/16-finals | Rybakina E. | Muguruza G. | 2:0 (6:3, 6:1) | details | 17.08.2022 |
 Canada: Toronto - Singles - Main |
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| 1/8-finals | Bencic B. | Muguruza G. | 2:0 (6:1, 6:3) | details | 12.08.2022 |
| 1/16-finals | Kanepi K. | Muguruza G. | 0:2 (4:6, 4:6) | details | 11.08.2022 |
| USA: San Jose - Singles - Main |
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| 1/16-finals | Giorgi C. | Muguruza G. | CAN. | details | 01.08.2022 |
 United Kingdom: Wimbledon - Singles - Main |
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| 1/64-finals | Muguruza G. | Minnen G. | 0:2 (4:6, 0:6) | details | 29.06.2022 |
| United Kingdom: Eastbourne - Singles - Main |
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| 1/8-finals | Muguruza G. | Giorgi C. | 0:2 (5:7, 3:6) | details | 22.06.2022 |
| 1/16-finals | Muguruza G. | Frech M. | 2:0 (6:1, 7:67) | details | 20.06.2022 |
 Germany: Berlin - Singles - Main |
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| 1/16-finals | Petkovic A. | Muguruza G. | 2:0 (7:68, 6:4) | details | 14.06.2022 |
| France: French Open - Singles - Main |
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| 1/64-finals | Kanepi K. | Muguruza G. | 2:1 (2:6, 6:3, 6:4) | details | 22.05.2022 |
 Morocco: Rabat - Singles - Main |
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| 1/8-finals | Muguruza G. | Trevisan M. | 1:2 (6:2, 4:6, 1:6) | details | 18.05.2022 |
| 1/16-finals | Muguruza G. | Danilina A. | 2:0 (6:3, 6:2) | details | 16.05.2022 |
 Italy: Rome - Singles - Main |
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| 1/16-finals | Muguruza G. | Putintseva Y. | 1:2 (6:3, 64:7, 1:6) | details | 11.05.2022 |
 Spain: Madrid - Singles - Main |
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| 1/16-finals | Kalinina A. | Muguruza G. | 2:0 (6:3, 6:0) | details | 01.05.2022 |
| 1/32-finals | Tomljanovic A. | Muguruza G. | 0:2 (5:7, 2:6) | details | 29.04.2022 |
| USA: Miami - Singles - Main |
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| 1/32-finals | Muguruza G. | Davis L. | CAN. | details | 25.03.2022 |
| USA: Indian Wells - Singles - Main |
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| 1/32-finals | Riske-Amritraj A. | Muguruza G. | 2:1 (0:6, 6:3, 6:1) | details | 12.03.2022 |
 Qatar: Doha - Singles - Main |
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| Quarter-finals | Muguruza G. | Ostapenko J. | 0:2 (2:6, 2:6) | details | 24.02.2022 |
| 1/8-finals | Muguruza G. | Brengle M. | 2:0 (6:0, 6:2) | details | 23.02.2022 |
| 1/16-finals | Muguruza G. | Cirstea S. | 2:0 (7:64, 6:1) | details | 21.02.2022 |
| United Arab Emirates: Dubai - Singles - Main |
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| 1/8-finals | Kudermetova V. | Muguruza G. | 2:1 (3:6, 6:4, 6:4) | details | 16.02.2022 |
| 1/16-finals | Siniakova K. | Muguruza G. | 1:2 (65:7, 6:2, 2:6) | details | 15.02.2022 |
| 1/16-finals | Collins D. | Muguruza G. | CAN. | details | 14.02.2022 |
| Australia: Australian Open - Singles - Main |
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| 1/32-finals | Cornet A. | Muguruza G. | 2:0 (6:3, 6:3) | details | 20.01.2022 |
| 1/64-finals | Burel C. | Muguruza G. | 0:2 (3:6, 4:6) | details | 18.01.2022 |
| Australia: Sydney - Singles - Main |
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| Quarter-finals | Kasatkina D. | Muguruza G. | 2:0 (6:4, 6:4) | details | 13.01.2022 |
| 1/8-finals | Alexandrova E. | Muguruza G. | 0:2 (1:6, 64:7) | details | 12.01.2022 |
 World: Finals - Guadalajara - Singles - Play Offs |
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| Final | Muguruza G. | Kontaveit A. | 2:0 (6:3, 7:5) | details | 18.11.2021 |
| Semi-finals | Badosa P. | Muguruza G. | 0:2 (3:6, 3:6) | details | 16.11.2021 |
| World: Finals - Guadalajara - Singles - Main |
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| Group B | Muguruza G. | Kontaveit A. | 2:0 (6:4, 6:4) | details | 15.11.2021 |
| Group B | Krejcikova B. | Muguruza G. | 1:2 (6:2, 3:6, 4:6) | details | 13.11.2021 |
| Group B | Pliskova Ka. | Muguruza G. | 2:1 (4:6, 6:2, 7:66) | details | 11.11.2021 |
 Russia: Moscow - Singles - Main |
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| Quarter-finals | Kontaveit A. | Muguruza G. | 2:0 (6:1, 6:1) | details | 22.10.2021 |
| 1/8-finals | Martincova T. | Muguruza G. | 1:2 (4:6, 6:4, 3:6) | details | 20.10.2021 |
| USA: Indian Wells - Singles - Main |
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| 1/32-finals | Tomljanovic A. | Muguruza G. | 2:1 (6:3, 1:6, 6:3) | details | 09.10.2021 |
| USA: Chicago 2 - Singles - Main |
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| Final | Jabeur O. | Muguruza G. | 1:2 (6:3, 3:6, 0:6) | details | 03.10.2021 |
| Semi-finals | Vondrousova M. | Muguruza G. | WO. | details | 02.10.2021 |
| Quarter-finals | Hontama M. | Muguruza G. | 0:2 (3:6, 2:6) | details | 01.10.2021 |