 USA: Sunrise - Singles - Main |
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| 1/16-finals | Grosjean S. | Hajek J. | 1:2 (2:6, 7:6, 0:6) | details | 16.03.2010 |
| USA: Indian Wells - Singles - Qualification |
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| 1/32-finals | Anderson K. | Grosjean S. | 2:0 (6:3, 7:6) | details | 09.03.2010 |
| USA: Delray Beach - Singles - Main |
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| 1/16-finals | Grosjean S. | Brands D. | 1:2 (6:3, 3:6, 2:6) | details | 23.02.2010 |
 Australia: Australian Open - Singles - Main |
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| 1/64-finals | Grosjean S. | Ilhan M. | 0:3 (4:6, 3:6, 5:7) | details | 19.01.2010 |
 New Zealand: Auckland - Singles - Main |
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| 1/8-finals | Melzer J. | Grosjean S. | 2:1 (6:2, 6:7, 7:6) | details | 13.01.2010 |
| 1/16-finals | Mayer F. | Grosjean S. | 1:2 (3:6, 6:3, 3:6) | details | 12.01.2010 |
 France: Paris - Singles - Main |
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| 1/32-finals | Grosjean S. | Ljubicic I. | 0:2 (6:7, 4:6) | details | 09.11.2009 |
| France: Lyon 2 - Singles - Main |
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| 1/16-finals | Kiefer N. | Grosjean S. | 2:1 (4:6, 7:6, 7:6) | details | 28.10.2009 |
| France: Orleans - Singles - Main |
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| | Ascione T. | Grosjean S. | 2:0 (6:4, 6:4) | details | 21.10.2009 |
| France: Metz - Singles - Main |
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| 1/8-finals | Monfils G. | Grosjean S. | 2:0 (6:1, 6:1) | details | 24.09.2009 |
| 1/16-finals | Grosjean S. | Mahut N. | 2:0 (7:6, 7:5) | details | 23.09.2009 |
| | Grosjean S. | Nieminen J. | CAN. | details | 23.09.2009 |
| USA: Newport - Singles - Main |
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| 1/16-finals | Kim K. | Grosjean S. | 1:0 RET. (4:6, 6:3) | details | 09.07.2009 |
 United Kingdom: London - Singles - Main |
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| 1/32-finals | Grosjean S. | Ferrero J. C. | 2:0 RET. (2:6, 1:2) | details | 09.06.2009 |
| United Kingdom: Nottingham - Singles - Main |
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| 1/8-finals | Grosjean S. | Bozoljac I. | WO. | details | 04.06.2009 |
| 1/16-finals | Cox D. | Grosjean S. | 0:2 (1:6, 3:6) | details | 03.06.2009 |
| France: Lyon 2 - Singles - Main |
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| 1/16-finals | Ginepri R. | Grosjean S. | 2:1 (6:7, 6:4, 6:4) | details | 21.10.2008 |
| USA: US Open - Singles - Main |
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| 1/64-finals | Grosjean S. | Mathieu P. | 1:3 (7:6, 6:7, 3:6, 2:6) | details | 26.08.2008 |
| USA: New Haven - Singles - Main |
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| 1/32-finals | Odesnik W. | Grosjean S. | 2:0 (7:5, 6:4) | details | 18.08.2008 |
| USA: Washington - Singles - Main |
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| 1/16-finals | Grosjean S. | Schwank E. | 1:2 (3:6, 6:4, 3:6) | details | 13.08.2008 |
| USA: Los Angeles - Singles - Main |
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| 1/16-finals | Spadea V. | Grosjean S. | 2:1 (6:3, 3:6, 6:3) | details | 05.08.2008 |
| United Kingdom: Wimbledon - Singles - Main |
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| 1/32-finals | Gasquet R. | Grosjean S. | 2:0 RET. (6:2, 6:2) | details | 26.06.2008 |
| 1/64-finals | Grosjean S. | Starace P. | 3:0 (6:2, 7:5, 6:1) | details | 24.06.2008 |
| United Kingdom: London - Singles - Main |
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| 1/16-finals | Grosjean S. | Murray A. | 0:0 RET. (0:2) | details | 10.06.2008 |
| 1/32-finals | Grosjean S. | De Voest R. | 2:0 (7:6, 6:1) | details | 09.06.2008 |
 Monaco: Monte Carlo - Singles - Main |
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| 1/32-finals | Grosjean S. | Karlovic I. | 1:1 RET. (6:4, 4:6, 1:4) | details | 22.04.2008 |
| USA: Miami - Singles - Main |
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| 1/32-finals | Grosjean S. | Stepanek R. | 0:2 (3:6, 3:6) | details | 28.03.2008 |
| 1/64-finals | Kuerten G. | Grosjean S. | 0:2 (1:6, 5:7) | details | 26.03.2008 |
| USA: Indian Wells - Singles - Main |
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| 1/64-finals | Grosjean S. | Soderling R. | 0:2 (3:6, 3:6) | details | 13.03.2008 |
| USA: Las Vegas - Singles - Main |
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| 1/16-finals | Querrey S. | Grosjean S. | 2:1 (6:2, 4:6, 7:6) | details | 03.03.2008 |
| France: Marseille - Singles - Main |
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| 1/16-finals | Wawrinka S. | Grosjean S. | 2:1 (3:6, 6:4, 6:4) | details | 12.02.2008 |
| Australia: Australian Open - Main |
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| 1/16-finals | Blake J. | Grosjean S. | 3:2 (4:6, 2:6, 6:0, 7:6, 6:2) | details | 19.01.2008 |