World: Finals - Cancun - Doubles - Play Offs |
| Semi-finals | Siegemund L./Zvonareva V. | Hunter S./Mertens E. | 2:1 (3:6, 6:3, 10:5) | dettagli | 05.11.2023 |
World: Finals - Cancun - Doubles - Main |
| Group B | Hunter S./Mertens E. | Krawczyk D./Schuurs D. | 2:0 (6:2, 6:3) | dettagli | 02.11.2023 |
| Group B | Hunter S./Mertens E. | Melichar-Martinez N./Perez E. | 2:0 (7:5, 6:4) | dettagli | 01.11.2023 |
| Group B | Hunter S./Mertens E. | Aoyama S./Shibahara E. | 2:0 (6:4, 6:2) | dettagli | 30.10.2023 |
China: Beijing - Doubles - Main |
| 1/8-finals | Hunter S./Mertens E. | Chan H-C./Olmos G. | 0:2 (1:6, 2:6) | dettagli | 03.10.2023 |
Mexico: Guadalajara - Doubles - Main |
| Final | Hunter S./Mertens E. | Dabrowski G./Routliffe E. | 2:1 (3:6, 6:2, 10:4) | dettagli | 23.09.2023 |
| Semi-finals | Hunter S./Mertens E. | Dolehide C./Muhammad A. | 2:0 (7:5, 6:3) | dettagli | 23.09.2023 |
| Quarter-finals | Hunter S./Mertens E. | Guarachi A./Niculescu M. | 2:0 (6:3, 6:1) | dettagli | 21.09.2023 |
| 1/8-finals | Hunter S./Mertens E. | Mattek-Sands B./Mladenovic K. | 2:0 (6:2, 6:2) | dettagli | 21.09.2023 |
USA: US Open - Doubles - Main |
| 1/32-finals | Collins D./Kichenok N. | Hunter S./Mertens E. | 2:0 (6:4, 6:3) | dettagli | 31.08.2023 |
USA: Cincinnati - Doubles - Main |
| Semi-finals | Parks A./Townsend T. | Hunter S./Mertens E. | 2:0 (6:4, 6:2) | dettagli | 18.08.2023 |
| Quarter-finals | Pavlyuchenkova A./Stefani L. | Hunter S./Mertens E. | 0:2 (2:6, 1:6) | dettagli | 18.08.2023 |
| 1/8-finals | Begu I./Sorribes Tormo S. | Hunter S./Mertens E. | 0:2 (4:6, 1:6) | dettagli | 17.08.2023 |
Canada: Montreal - Doubles - Main |
| Semi-finals | Krawczyk D./Schuurs D. | Hunter S./Mertens E. | 2:1 (6:3, 3:6, 11:9) | dettagli | 12.08.2023 |
| Quarter-finals | Kichenok L./Ostapenko J. | Hunter S./Mertens E. | 0:2 (4:6, 4:6) | dettagli | 11.08.2023 |
| 1/8-finals | Kostyuk M./Zhang S. | Hunter S./Mertens E. | 0:2 (4:6, 1:6) | dettagli | 11.08.2023 |
United Kingdom: Wimbledon - Doubles - Main |
| Final | Hunter S./Mertens E. | Hsieh S-W./Strycova B. | 0:2 (5:7, 4:6) | dettagli | 16.07.2023 |
| Semi-finals | Dolehide C./Zhang S. | Hunter S./Mertens E. | 0:2 (1:6, 1:6) | dettagli | 14.07.2023 |
| Quarter-finals | Hunter S./Mertens E. | Bains N./Lumsden M. | 2:0 (6:2, 6:1) | dettagli | 12.07.2023 |
| 1/8-finals | Hunter S./Mertens E. | Skoch M./Vondrousova M. | WO. | dettagli | 11.07.2023 |
| 1/16-finals | Hunter S./Mertens E. | Begu I./Kalinina A. | 1:0 RET. (6:2, 2:0) | dettagli | 09.07.2023 |
France: French Open - Doubles - Main |
| 1/8-finals | Hunter S./Mertens E. | Kudermetova V./Samsonova L. | 0:2 (3:6, 4:6) | dettagli | 05.06.2023 |
| 1/16-finals | Hunter S./Mertens E. | Gamarra Martins I./Shymanovich I. | 2:0 (7:64, 6:1) | dettagli | 03.06.2023 |
| 1/32-finals | Hunter S./Mertens E. | Collins D./Navarro E. | 2:0 (6:2, 6:2) | dettagli | 02.06.2023 |
Italy: Rome - Doubles - Main |
| Final | Gauff C./Pegula J. | Hunter S./Mertens E. | 0:2 (4:6, 4:6) | dettagli | 20.05.2023 |
| Semi-finals | Hunter S./Mertens E. | Bouzkova M./Mattek-Sands B. | 2:0 (7:5, 6:4) | dettagli | 18.05.2023 |
| Quarter-finals | Babos T./Danilina A. | Hunter S./Mertens E. | 0:2 (4:6, 2:6) | dettagli | 15.05.2023 |
| 1/8-finals | Moratelli A./Rosatello C. | Hunter S./Mertens E. | 0:2 (1:6, 66:7) | dettagli | 14.05.2023 |
| 1/16-finals | Flipkens K./Rosolska A. | Hunter S./Mertens E. | 1:2 (0:6, 7:66, 4:10) | dettagli | 11.05.2023 |
Spain: Madrid - Doubles - Main |
| 1/8-finals | Hunter S./Mertens E. | Niculescu M./Ninomiya M. | 1:2 (4:6, 6:2, 8:10) | dettagli | 30.04.2023 |
| 1/16-finals | Hunter S./Mertens E. | Kasatkina D./Trevisan M. | 2:0 (6:3, 6:3) | dettagli | 29.04.2023 |
USA: Miami - Doubles - Main |
| Quarter-finals | Hunter S./Mertens E. | Gauff C./Pegula J. | 1:2 (7:64, 5:7, 2:10) | dettagli | 31.03.2023 |
| 1/8-finals | Hunter S./Mertens E. | Niculescu M./Rosolska A. | 2:0 (6:3, 6:2) | dettagli | 26.03.2023 |
| 1/16-finals | Hunter S./Mertens E. | Kato M./Sutjiadi A. | 2:0 (6:3, 7:61) | dettagli | 24.03.2023 |
USA: Indian Wells - Doubles - Main |
| Quarter-finals | Krejcikova B./Siniakova K. | Hunter S./Mertens E. | 2:0 (6:3, 6:3) | dettagli | 16.03.2023 |
| 1/8-finals | Collins D./Stearns P. | Hunter S./Mertens E. | 0:2 (4:6, 4:6) | dettagli | 14.03.2023 |
| 1/16-finals | Badosa P./Rybakina E. | Hunter S./Mertens E. | 0:2 (62:7, 3:6) | dettagli | 12.03.2023 |
Australia: Australian Open - Doubles - Main |
| Quarter-finals | Hunter S./Mertens E. | Kostyuk M./Ruse G. | 1:2 (66:7, 6:2, 4:6) | dettagli | 25.01.2023 |
| 1/8-finals | Hunter S./Mertens E. | Golubic V./Niculescu M. | 2:0 (6:2, 6:2) | dettagli | 23.01.2023 |
| 1/16-finals | Hunter S./Mertens E. | Babos T./Mladenovic K. | 2:0 (6:3, 6:3) | dettagli | 22.01.2023 |
| 1/32-finals | Hunter S./Mertens E. | Kudermetova V./Samsonova L. | 2:1 (2:6, 7:66, 6:1) | dettagli | 20.01.2023 |